Change the hardness of the alloy based on changing the composition of aluminum alloys

Abstract

This article analyzes the influence of germanium on aluminum alloys. The article examines how germanium oxide is introduced into its composition during melting of aluminum-manganese, aluminum-copper, aluminum-magnesium alloys and its hardness changes. Based on the results of the conducted research, the conclusions and suggestions of the authors are presented at the end of the article.

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Tursunbaev Sarvar, Dovulov Shukhrat, Tadjiyev Nuritdin, Murodov Sobirjon, Turakhujaeva Azizakhon, & Rakhmonova Mokhinur. (2025). Change the hardness of the alloy based on changing the composition of aluminum alloys. American Journal Of Applied Science And Technology, 5(01), 18–22. https://doi.org/10.37547/ajast/Volume05Issue01-05
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Abstract

This article analyzes the influence of germanium on aluminum alloys. The article examines how germanium oxide is introduced into its composition during melting of aluminum-manganese, aluminum-copper, aluminum-magnesium alloys and its hardness changes. Based on the results of the conducted research, the conclusions and suggestions of the authors are presented at the end of the article.


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American Journal of Applied Science and Technology

18

https://theusajournals.com/index.php/ajast

VOLUME

Vol.05 Issue01 2025

PAGE NO.

18-22

DOI

10.37547/ajast/Volume05Issue01-05



Change the hardness of the alloy based on changing the
composition of aluminum alloys

Tursunbaev Sarvar

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Dovulov Shukhrat

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Tadjiyev Nuritdin

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Murodov Sobirjon

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Turakhujaeva Azizakhon

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Rakhmonova Mokhinur

Tashkent State Technical University named after Islam Karimov, 100095, University 2, Tashkent, Uzbekistan

Received:

20 October 2024;

Accepted:

22 December 2024;

Published:

12 January 2025

Abstract:

This article analyzes the influence of germanium on aluminum alloys. The article examines how

germanium oxide is introduced into its composition during melting of aluminum-manganese, aluminum-copper,
aluminum-magnesium alloys and its hardness changes. Based on the results of the conducted research, the
conclusions and suggestions of the authors are presented at the end of the article.

Keywords:

Hardness, alloying, aluminum, manganese, copper, magnesium, germanium, furnace.

Introduction:

Aluminum alloys have better mechanical

and technological properties than pure aluminum.
Therefore, aluminum alloys are widely used in
mechanical engineering, aircraft manufacturing,
shipbuilding, construction and agriculture. Aluminum
stands out among structural materials due to its
important properties (relative strength, electrical and
thermal conductivity, corrosion resistance). Aluminum
forms solid solutions with different compositions that
look like alloying elements. Due to the growing demand
for aluminum alloys in industry, scientists around the
world are conducting research to improve their

properties. In particular, research aimed at improving
the properties of aluminum alloys by introducing
various alloying elements into them was carried out by
the Iranian scientist S.G. Shabestari and others studied
the influence of copper and the state of solidification
on the microstructure and mechanical properties of Al-
Si-Mg alloys. The researchers used aluminum alloy
grade A356 with a copper content of 0.2

2.5%, cast

under various solidification conditions (in sand,
graphite, copper, and cast iron molds). The highest
tensile strength was obtained with heat treatment of
alloys (T6), mold cooling rate (graphite) and copper


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American Journal of Applied Science and Technology (ISSN: 2771-2745)

content up to 1.5%. The best mechanical properties
were demonstrated by dissolving approximately 1.5%
Cu in the Al-Si-Mg alloy in graphite molds. In this article,
the authors studied the effect of introducing
germanium oxide into aluminum and its mechanical
properties, including hardness.

METHODS

The studies were conducted on aluminum alloys in the
aluminum-copper,

aluminum-magnesium

and

aluminum-manganese systems. These alloys contain
germanium oxide. As a result of the introduction of this
compound, the oxygen contained in it was released,
and the germanium was absorbed by the alloy.
Germanium is located in period 4 th group,14 of the
periodic table of chemical elements, with atomic

number 32. Denoted as Ge (Germany), Germanium is a
grey-white intermediate optical material that is shiny
like metals. Like silicon, it is a semiconductor.
Germanium is usually extracted from nickel and
tungsten ores as a semi-metallic compound. It is also
obtained from the composition of silicates. After very
complex processing of the ore, germanium oxide is
released in the form of GeO2. In the experiments,
aluminum alloys were melted in a resistance furnace
with the addition of germanium oxide. First, for
comparison, samples were cast in aluminum alloys
without the addition of germanium oxide. At the next
stage, the element germanium was added to the alloys
of the selected grade in the form of oxide in an amount
of 0.1% to 0.3% relative to the batch.

Fig.1. Processed samples.

From each selected alloy grade, samples with three
different compositions were cast. The cast samples
were cut on a lathe to the required size and shape. The

cut and processed samples are shown in figure1. The
following tables present the chemical composition of
the samples.

Table 1.

Alloy in the aluminum-manganese system

Brand

Percentage of elements by mass, %

Al

Si

Fe

Cu

Mn

Mg

Ti

Be

Zn

Ge

Cr

1

АМц

96,3-99

0,6

0,7

0,05-0,2

1-1,5

-

-

-

0,1

-

-

2

АМц

96,3-99

0,6

0,7

0,05-0,2

1-1,5

-

-

-

0,1

1

-

3

АМц

96,3-99

0,6

0,7

0,05-0,2

1-1,5

-

-

-

0,1

2

-

4

АМц

96,3-99

0,6

0,7

0,05-0,2

1-1,5

-

-

-

0,1

3

-

Table 2.

Alloy in the aluminum-copper system


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American Journal of Applied Science and Technology (ISSN: 2771-2745)

Brand

Percentage of elements by mass, %

Al

Si

Fe

Cu

Mn

Mg

Ti

Be

Zn

Ge

Cr

1

Д16

91-94,7 0,5

0,5

3,8-4,9

0,3-0,9

1,2-1,8

0,1

-

0,3

-

0,5

2

Д16

91-94,7 0,5

0,5

3,8-4,9

0,3-0,9

1,2-1,8

0,1

-

0,3

1

0,5

3

Д16

91-94,7 0,5

0,5

3,8-4,9

0,3-0,9

1,2-1,8

0,1

-

0,3

2

0,5

4

Д16

91-94,7 0,5

0,5

3,8-4,9

0,3-0,9

1,2-1,8

0,1

-

0,3

3

0,5

Table 3.

Alloy in the aluminum-magnesium system

Brand

Percentage of elements by mass, %

Al

Si

Fe

Cu

Mn

Mg

Ti

Be

Zn

Ge

Cr

1

АМг5 91,9-94 0,5

0,5

0,1

0,3-0,8

4,8-5,8

0,1

0,005

0,2

-

-

2

АМг5 91,9-94 0,5

0,5

0,1

0,3-0,8

4,8-5,8

0,1

0,005

0,2

1

-

3

АМг5 91,9-94 0,5

0,5

0,1

0,3-0,8

4,8-5,8

0,1

0,005

0,2

2

-

4

АМг5 91,9-94 0,5

0,5

0,1

0,3-0,8

4,8-5,8

0,1

0,005

0,2

3

-

RESULTS AND DISCUSSIONS

The cut and processed samples were ground and their
hardness was measured. Hardness was measured on

the Brinell scale. To measure hardness, a hardness

tester “Rockwell type hardness tester FR” was used.

(Fig. 2).

Fig. 2. Rockwell type hardness tester FR.


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American Journal of Applied Science and Technology (ISSN: 2771-2745)

The hardness of the samples was measured at three
different points on the same surface. The results of the

hardness measurements are presented in the diagrams
below.

CONCLUSION

Based on the experience gained, the following
conclusions can be drawn. Overall, germanium oxide
did not have a positive effect on the hardness of
aluminum alloys. Germanium oxide did not have a
significant effect on the hardness of the alloy in the
aluminum-manganese system. However, this sharply
reduced the hardness of alloys in the aluminum-copper
and aluminum-magnesium systems. Therefore, it is
recommended to include germanium oxide in the alloy
composition together with other elements. For
example, studies have shown that its inclusion in
combination with strontium and silicon increases the
hardness of the alloy.

REFERENCES

Sarvar, T., Nodir, T., Mardonov, U., Saydumarov, B.,
Kulmuradov, D., & Boltaeva, M. (2024). EFFECTS OF

GERMANIUM

(GE)

ON

HARDNESS

AND

MICROSTRUCTURE OF AL-MG, AL-CU, AL-MN SYSTEM
ALLOYS. International Journal of Mechatronics and
Applied Mechanics, (16), 179-184.

Sarvar, T., Nodir, T., Shohista, S., Anvar, T., & Mashhura,
M. (2024). DEVELOPMENT OF A MATHEMATICAL
MODEL OF THE EFFECT OF LITHIUM ON THE WEAR
RESISTANCE PROPERTIES OF ALUMINUM-LITHIUM
ALLOYS. American Journal Of Applied Science And
Technology, 4(01), 37-41.

Tan, C. F., & Radzai, S. M. (2009). Effect of hardness test
on precipitation hardening aluminium alloy 6061-T6.
Chiang Mai Journal of Science, 36(3), 276-286.

Asgharzadeh, A., Nazari Tiji, S. A., Esmaeilpour, R., Park,
T., & Pourboghrat, F. (2020). Determination of
hardness-strength and-flow behavior relationships in
bulged aluminum alloys and verification by FE analysis
on Rockwell hardness test. The International Journal of

0

5

10

15

20

25

30

АМц

Д16

АМг5

АМц

Д16

АМг5

3 % Ge

22.43

15.93

5.53

2% Ge

22.22

13.9

9.94

1 % Ge

22.53

22.43

10.93

0 % Ge

24.27

25.5

22.53

Results of hardness measurments


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American Journal of Applied Science and Technology

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American Journal of Applied Science and Technology (ISSN: 2771-2745)

Advanced Manufacturing Technology, 106, 315-331.

Tursunbaev, S., Turakhodjaev, N., Odilov, F.,
Mardanokulov, S., & Zokirov, R. (2023). Change in wear
resistance of alloy when alloying aluminium alloy with
germanium oxide. In E3S Web of Conferences (Vol. 401,
p. 05001). EDP Sciences.

Sarvar, T., Nodir, T., & Sharofuddin, M. (2022). Changes
in the Hardness of Aluminum Alloys in the Influence of
Lithium. Eurasian Journal of Engineering and
Technology, 8, 56-60.

Kim, K. C., Park, S. H., Na, M. Y., Chang, H. J., Kim, W. T.,
Mattern, N., ... & Kim, D. H. (2015). Formation of nano-
porous GeOx by de-alloying of an Al

Ge

Mn

amorphous alloy. Scripta Materialia, 104, 49-52.

Tursunbaev, S., Turakhodjaev, N., Saidxodjayeva, S., &
Hudoykulov, S. (2023). INFLUENCE OF ALLOYING
ELEMENTS ON ALUMINUM ALLOYS. International
Journal of Advance Scientific Research, 3(09), 46-50.

Davis, R. M., & Koch, C. C. (1987). Mechanical alloying
of brittle components: silicon and germanium. Scripta
metallurgica, 21(3), 305-310.

Tursunbaev, S., Turakhodjaev, N., Mardonakulov, S., &
Hudoykulov, S. (2023). EFFECT OF GERMANIUM OXIDE
ON ALUMINUM ALLOY STRUCTURE. American Journal
of Applied Science and Technology, 3(09), 10-13.

Tursunbaev, S., Umarova, D., Kuchkorova, M., &
Baydullaev, A. (2022, June). Study of machining
accuracy in ultrasonic elliptical vibration cutting of
alloyed iron alloy carbon with a germanium. In Journal
of Physics: Conference Series (Vol. 2176, No. 1, p.
012053). IOP Publishing.

Hill, R., Storåkers, B., & Zdunek, A. B. (1989). A
theoretical study of the Brinell hardness test.
Proceedings of the Royal Society of London. A.
Mathematical and Physical Sciences, 423(1865), 301-
330.

Ponnusamy, P., Rahman Rashid, R. A., Masood, S. H.,
Ruan, D., & Palanisamy, S. (2020). Mechanical
properties of SLM-printed aluminium alloys: a review.
Materials, 13(19), 4301.

Tursunbaev, S., Turakhodjayev, N., Mardanokulov, S., &
Tashbulatov, S. (2023). Influence of germanium oxide
on the mechanical properties of aluminum alloy.
Eurasian Journal of Engineering and Technology, 16,
91-94.

Sarvar, T. (2022). Changes in its Wear Resistance When
Alloying Aluminum Alloys with Lithium. Texas Journal of
Engineering and Technology, 12, 32-36.

Sarvar, T., Nodir, T., Shoxista, S., Ruslan, Z., &
Sharofuddin, M. (2022). The effect of lithium fluoride
compound on slag decomposition in the process of

casting aluminum prepared details. Asian Journal Of
Multidimensional Research, 11(7), 46-50.

Tashbulatov, S., Tursunbaev, S., Omonov, F., Zokirov,
R., & Shaxzod, S. (2024, October). ANALYSIS OF SLAG
FORMATION AND THEIR CHARACTERISTICS DURING
MELTING OF FERROUS METAL ALLOYS. In Uz
Conferences (Vol. 1, No. 1).

Xu, R., Zhao, H., Li, J., Liu, R., & Wang, W. K. (2006).
Microstructures of the eutectic and hypereutectic Al

Ge alloys solidified under different pressures. Materials
Letters, 60(6), 783-785.

References

Sarvar, T., Nodir, T., Mardonov, U., Saydumarov, B., Kulmuradov, D., & Boltaeva, M. (2024). EFFECTS OF GERMANIUM (GE) ON HARDNESS AND MICROSTRUCTURE OF AL-MG, AL-CU, AL-MN SYSTEM ALLOYS. International Journal of Mechatronics and Applied Mechanics, (16), 179-184.

Sarvar, T., Nodir, T., Shohista, S., Anvar, T., & Mashhura, M. (2024). DEVELOPMENT OF A MATHEMATICAL MODEL OF THE EFFECT OF LITHIUM ON THE WEAR RESISTANCE PROPERTIES OF ALUMINUM-LITHIUM ALLOYS. American Journal Of Applied Science And Technology, 4(01), 37-41.

Tan, C. F., & Radzai, S. M. (2009). Effect of hardness test on precipitation hardening aluminium alloy 6061-T6. Chiang Mai Journal of Science, 36(3), 276-286.

Asgharzadeh, A., Nazari Tiji, S. A., Esmaeilpour, R., Park, T., & Pourboghrat, F. (2020). Determination of hardness-strength and-flow behavior relationships in bulged aluminum alloys and verification by FE analysis on Rockwell hardness test. The International Journal of Advanced Manufacturing Technology, 106, 315-331.

Tursunbaev, S., Turakhodjaev, N., Odilov, F., Mardanokulov, S., & Zokirov, R. (2023). Change in wear resistance of alloy when alloying aluminium alloy with germanium oxide. In E3S Web of Conferences (Vol. 401, p. 05001). EDP Sciences.

Sarvar, T., Nodir, T., & Sharofuddin, M. (2022). Changes in the Hardness of Aluminum Alloys in the Influence of Lithium. Eurasian Journal of Engineering and Technology, 8, 56-60.

Kim, K. C., Park, S. H., Na, M. Y., Chang, H. J., Kim, W. T., Mattern, N., ... & Kim, D. H. (2015). Formation of nano-porous GeOx by de-alloying of an Al–Ge–Mn amorphous alloy. Scripta Materialia, 104, 49-52.

Tursunbaev, S., Turakhodjaev, N., Saidxodjayeva, S., & Hudoykulov, S. (2023). INFLUENCE OF ALLOYING ELEMENTS ON ALUMINUM ALLOYS. International Journal of Advance Scientific Research, 3(09), 46-50.

Davis, R. M., & Koch, C. C. (1987). Mechanical alloying of brittle components: silicon and germanium. Scripta metallurgica, 21(3), 305-310.

Tursunbaev, S., Turakhodjaev, N., Mardonakulov, S., & Hudoykulov, S. (2023). EFFECT OF GERMANIUM OXIDE ON ALUMINUM ALLOY STRUCTURE. American Journal of Applied Science and Technology, 3(09), 10-13.

Tursunbaev, S., Umarova, D., Kuchkorova, M., & Baydullaev, A. (2022, June). Study of machining accuracy in ultrasonic elliptical vibration cutting of alloyed iron alloy carbon with a germanium. In Journal of Physics: Conference Series (Vol. 2176, No. 1, p. 012053). IOP Publishing.

Hill, R., Storåkers, B., & Zdunek, A. B. (1989). A theoretical study of the Brinell hardness test. Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences, 423(1865), 301-330.

Ponnusamy, P., Rahman Rashid, R. A., Masood, S. H., Ruan, D., & Palanisamy, S. (2020). Mechanical properties of SLM-printed aluminium alloys: a review. Materials, 13(19), 4301.

Tursunbaev, S., Turakhodjayev, N., Mardanokulov, S., & Tashbulatov, S. (2023). Influence of germanium oxide on the mechanical properties of aluminum alloy. Eurasian Journal of Engineering and Technology, 16, 91-94.

Sarvar, T. (2022). Changes in its Wear Resistance When Alloying Aluminum Alloys with Lithium. Texas Journal of Engineering and Technology, 12, 32-36.

Sarvar, T., Nodir, T., Shoxista, S., Ruslan, Z., & Sharofuddin, M. (2022). The effect of lithium fluoride compound on slag decomposition in the process of casting aluminum prepared details. Asian Journal Of Multidimensional Research, 11(7), 46-50.

Tashbulatov, S., Tursunbaev, S., Omonov, F., Zokirov, R., & Shaxzod, S. (2024, October). ANALYSIS OF SLAG FORMATION AND THEIR CHARACTERISTICS DURING MELTING OF FERROUS METAL ALLOYS. In Uz Conferences (Vol. 1, No. 1).

Xu, R., Zhao, H., Li, J., Liu, R., & Wang, W. K. (2006). Microstructures of the eutectic and hypereutectic Al–Ge alloys solidified under different pressures. Materials Letters, 60(6), 783-785.