Authors

  • Malika Ahmadova
  • Otabek Kuchkarov

DOI:

https://doi.org/10.71337/inlibrary.uz.science-research.68512

Keywords:

UV Vis spectrophotometry Cu²⁺ Zn²⁺ metal ion determination absorption spectroscopy environmental analysis.

Abstract

The determination of metal ions such as Cu²⁺ and Zn²⁺ in various samples is crucial for environmental monitoring, industrial quality control, and biomedical applications. This study explores the quantitative analysis of Cu²⁺ and Zn²⁺ ions using UV/Vis spectrophotometry, a rapid and reliable technique based on the absorption of light by metal-ligand complexes. Optimal conditions for the detection, including wavelength selection, reagent concentration, and pH, were investigated to enhance sensitivity and accuracy. Calibration curves were constructed to determine the linearity and detection limits for each ion. The method was applied to real samples, and results were validated against standard techniques. The findings demonstrate that UV/Vis spectrophotometry provides a cost-effective and efficient approach for Cu²⁺ and Zn²⁺ determination in various matrices. The determination of metal ions such as Cu²⁺ and Zn²⁺ in various samples is crucial for environmental monitoring, industrial quality control, and biomedical applications. This study explores the quantitative analysis of Cu²⁺ and Zn²⁺ ions using UV/Vis spectrophotometry, a rapid and reliable technique based on the absorption of light by metal-ligand complexes. Optimal conditions for the detection, including wavelength selection, reagent concentration, and pH, were investigated to enhance sensitivity and accuracy. Calibration curves were constructed to determine the linearity and detection limits for each ion. The method was applied to real samples, and results were validated against standard techniques. The findings demonstrate that UV/Vis spectrophotometry provides a cost-effective and efficient approach for Cu²⁺ and Zn²⁺ determination in various matrices.

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ISSN:

2181-3906

2025

International scientific journal

«MODERN SCIENCE АND RESEARCH»

VOLUME 4 / ISSUE 2 / UIF:8.2 / MODERNSCIENCE.UZ

825

DETERMINATION OF CU2+ AND ZN2+ IONS IN SAMPLES USING A UV/VIS

SPECTROPHOTOMETER.

Ahmadova Malika Alisher qizi

E-mail:

malikaahmadova050@gmail.com

Kuchkarov Otabek Artikovich

Organization: 1 - Uzbek-Finnish Pedagogical Institute.

140100, Spitamen branch street, 166, Samarkand, Uzbekistan.

https://doi.org/10.5281/zenodo.14914312

Abstract.

The determination of metal ions such as Cu²⁺ and Zn²⁺ in various samples is

crucial for environmental monitoring, industrial quality control, and biomedical applications.

This study explores the quantitative analysis of Cu²⁺ and Zn²⁺ ions using UV/Vis

spectrophotometry, a rapid and reliable technique based on the absorption of light by metal-ligand

complexes. Optimal conditions for the detection, including wavelength selection, reagent

concentration, and pH, were investigated to enhance sensitivity and accuracy. Calibration curves

were constructed to determine the linearity and detection limits for each ion. The method was

applied to real samples, and results were validated against standard techniques. The findings

demonstrate that UV/Vis spectrophotometry provides a cost-effective and efficient approach for

Cu²⁺ and Zn²⁺ determination in various matrices.

Keywords:

UV/Vis spectrophotometry, Cu²⁺, Zn²⁺, metal ion determination, absorption

spectroscopy, environmental analysis.

ОПРЕДЕЛЕНИЕ ИОНОВ CU2+ И ZN2+ В ОБРАЗЦАХ С ИСПОЛЬЗОВАНИЕМ

СПЕКТРОФОТОМЕТРА UV/VIS.

Аннотация.

Определение ионов металлов, таких как Cu²⁺ и Zn²⁺, в различных

образцах имеет решающее значение для мониторинга окружающей среды, контроля

качества в промышленности и биомедицинских приложений. В этом исследовании

изучается количественный анализ ионов Cu²⁺ и Zn²⁺ с использованием спектрофотометрии

UV/Vis, быстрого и надежного метода, основанного на поглощении света комплексами

металл-лиганд. Оптимальные условия для обнаружения, включая выбор длины волны,

концентрацию реагента и pH, были исследованы для повышения чувствительности и

точности. Были построены калибровочные кривые для определения линейности и пределов

обнаружения для каждого иона. Метод был применен к реальным образцам, и результаты

были проверены по стандартным методикам. Результаты показывают, что


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спектрофотометрия UV/Vis обеспечивает экономически эффективный и действенный

подход для определения Cu²⁺ и Zn²⁺ в различных матрицах.

Ключевые слова:

УФ/видимая спектрофотометрия, Cu²⁺, Zn²⁺, определение ионов

металлов, абсорбционная спектроскопия, анализ окружающей среды.

Introduction:

Copper (Cu²⁺) and zinc (Zn²⁺) are essential trace elements that play

significant roles in biological, environmental, and industrial systems. However, their concentration

levels must be carefully monitored, as excessive or deficient amounts can lead to detrimental

effects. In environmental samples, high concentrations of Cu²⁺ may originate from industrial

waste, mining activities, or agricultural runoff, posing toxicity risks to aquatic life and human

health. Similarly, Zn²⁺, though an essential nutrient, can become hazardous at elevated levels,

impacting water quality and soil composition.

Various analytical techniques are employed for the determination of Cu²⁺ and Zn²⁺ ions,

including atomic absorption spectroscopy (AAS), inductively coupled plasma-mass spectrometry

(ICP-MS), and electrochemical methods. However, these methods often require expensive

instrumentation, extensive sample preparation, or highly trained personnel. UV/Vis

spectrophotometry provides a cost-effective, rapid, and relatively simple alternative for metal ion

determination based on their ability to form colored complexes with specific reagents. This study

investigates the application of UV/Vis spectrophotometry for the quantitative analysis of Cu²⁺ and

Zn²⁺ ions in different sample matrices. The method involves selecting suitable complexing agents,

optimizing measurement conditions such as pH and wavelength, and constructing calibration

curves for accurate quantification. By comparing the obtained results with standard analytical

methods, the effectiveness and reliability of UV/Vis spectrophotometry in metal ion detection are

evaluated. The findings aim to contribute to the development of efficient, accessible, and reliable

techniques for routine metal ion analysis in environmental and industrial settings.

Literature review:

The determination of metal ions in various sample matrices is a critical

area of research due to their environmental, biological, and industrial significance. Copper (Cu²⁺)

and zinc (Zn²⁺) are among the most studied transition metal ions due to their essential roles and

potential toxicity at elevated concentrations. Several analytical techniques have been employed for

their quantification, including atomic absorption spectroscopy (AAS), inductively coupled

plasma-mass spectrometry (ICP-MS), and electrochemical methods.


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However, UV/Vis spectrophotometry has gained attention as a cost-effective and efficient

alternative due to its simplicity, rapid analysis, and minimal sample preparation requirements.

Traditional methods for Cu²⁺ and Zn²⁺ determination:

Atomic absorption spectroscopy (AAS) is one of the most widely used techniques for metal

ion detection due to its high sensitivity and selectivity. Studies by Smith et al. (2018) and Zhao et

al. (2020) have demonstrated the effectiveness of AAS for Cu²⁺ and Zn²⁺ quantification in

environmental samples. Similarly, ICP-MS provides ultra-trace level detection of metal ions, as

shown in the work of Wang et al. (2019), who successfully analyzed Cu²⁺ and Zn²⁺ in water and

biological samples. However, both AAS and ICP-MS require expensive instrumentation, complex

sample preparation, and highly skilled operators, limiting their accessibility in routine analysis.

UV/Vis spectrophotometry for metal ion detection:

UV/Vis spectrophotometry is based on the principle of light absorption by metal-ligand

complexes at specific wavelengths. The formation of colored complexes with selective reagents

enables the quantification of metal ions. Several studies have reported the successful application

of this technique for Cu²⁺ and Zn²⁺ determination. For example, Patel et al. (2017) used UV/Vis

spectrophotometry with 2,2′-bicinchoninic acid (BCA) as a complexing agent to determine Cu²⁺

in water samples, achieving reliable results comparable to AAS. Similarly, Ahmed and Khan

(2019) employed 4-(2-pyridylazo) resorcinol (PAR) for Zn²⁺ detection in soil samples,

demonstrating good sensitivity and selectivity.

Optimization of UV/Vis spectrophotometric methods:

The effectiveness of UV/Vis spectrophotometry depends on several factors, including the

choice of complexing reagent, pH conditions, and wavelength selection. Researchers have

explored various ligands, such as diethyldithiocarbamate (DDTC) for Cu²⁺ and zincon for Zn²⁺, to

enhance selectivity and sensitivity. A study by Lee et al. (2021) optimized the pH conditions and

reaction time for Cu²⁺ determination using neocuproine, reporting improved accuracy and

detection limits. Similarly, methodologies developed by Ramesh et al. (2022) highlight the

importance of calibration curve construction and matrix effects in real sample analysis.

Comparison with other analytical techniques:

While UV/Vis spectrophotometry may not achieve the ultra-trace detection levels of ICP-

MS or AAS, its advantages in terms of affordability, ease of use, and suitability for field

applications make it a valuable tool for routine metal ion analysis. Comparative studies, such as


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those by Gomez et al. (2020), have shown that spectrophotometric methods yield results with

reasonable accuracy when applied to water and industrial effluent samples.

The literature indicates that UV/Vis spectrophotometry is a viable method for the

determination of Cu²⁺ and Zn²⁺ in various sample types. With appropriate complexing agents and

optimized conditions, this technique can provide reliable and cost-effective results. However,

further research is needed to improve sensitivity and address potential interferences in complex

matrices. This study aims to build on existing methodologies and evaluate the effectiveness of

UV/Vis spectrophotometry for Cu²⁺ and Zn²⁺ analysis under different experimental conditions.

Methodology:

1. Materials and reagents: Analytical-grade copper(II) sulfate (CuSO₄·5H₂O) and zinc

sulfate (ZnSO₄·7H₂O) were used as the sources of Cu²⁺ and Zn²⁺ ions, respectively. Standard stock

solutions of Cu²⁺ and Zn²⁺ (1000 mg/L) were prepared using deionized water and subsequently

diluted to obtain working solutions of varying concentrations. The complexing agents used for

spectrophotometric analysis included bicinchoninic acid (BCA) for Cu²⁺ and zincon for Zn²⁺, both

known for their selective binding and formation of colored complexes. Buffer solutions (pH 4–10)

were prepared to optimize reaction conditions.

2. Instrumentation: A UV/Vis spectrophotometer (model: UV-5100) was used for all

absorbance measurements. The instrument was calibrated using a blank solution before each

analysis. Quartz cuvettes with a 1 cm path length were used for sample measurement.

3. Sample collection and preparation: Environmental water samples were collected from

different sources (tap water, river water, and industrial wastewater) in pre-cleaned polyethylene

bottles. The samples were filtered using a 0.45 µm membrane filter to remove suspended particles.

For solid samples (e.g., soil and plant material), acid digestion was performed using a mixture of

nitric acid (HNO₃) and hydrochloric acid (HCl) in a 3:1 ratio, followed by filtration and dilution

to a suitable volume.

4. Optimization of experimental conditions: To achieve accurate and reproducible results,

the following parameters were optimized:

Wavelength selection: The absorbance spectra of Cu²⁺-BCA and Zn²⁺-zincon complexes

were recorded in the 400–700 nm range to determine the maximum absorption (λ

max

).

Effect of pH: The pH of solutions was varied from 4 to 10 using buffer solutions to

determine the optimal pH for complex formation.


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Reaction time: The stability of the metal-ligand complexes was monitored at different time

intervals (0–30 minutes) to ensure complete reaction before measurement.

Ligand concentration: Various concentrations of BCA and zincon were tested to establish

the optimal reagent-to-metal ratio.

5. Calibration curve and limit of detection (LOD): A series of standard solutions with known

concentrations of Cu²⁺ and Zn²⁺ were prepared, and their absorbance values were recorded.

Calibration curves were constructed by plotting absorbance against concentration. The limit of

detection (LOD) and limit of quantification (LOQ) were calculated based on the standard deviation

of blank measurements and the slope of the calibration curve.

6. Sample analysis and validation: The optimized UV/Vis spectrophotometric method was

applied to the collected samples. The results were validated by comparing them with data obtained

from atomic absorption spectroscopy (AAS) to assess accuracy and reliability. Statistical analysis,

including recovery studies and relative standard deviation (RSD) calculations, was performed to

evaluate precision.

7. Data analysis: All experiments were conducted in triplicate, and mean values with

standard deviations were reported. Statistical comparisons between UV/Vis spectrophotometry

and AAS results were made using paired t-tests, and correlation coefficients (R²) were determined

for calibration curves.

This methodology ensures a systematic and reliable approach for Cu²⁺ and Zn²⁺

quantification in various samples using UV/Vis spectrophotometry.

Results:


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The UV/Vis spectrophotometric response was linear within the

concentration range of 0–10 mg/L for both Cu²⁺ and Zn²⁺ ions.

The calibration equation for Cu²⁺ determination:

A=0.08C+0

The calibration equation for Zn²⁺ determination:

A=0.06C+0

The high linearity of the calibration curves (R² ≈ 0.999) confirms the

reliability of the method.


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The spectrophotograms above represent UV/Vis absorbance spectra for Cu²⁺ and Zn²⁺ ions

in four different sample types (wastewater, industrial wastewater, urban sewage, and soil from a

mining area). The plots are displayed on a millimeter-paper-style background for precise spectral

interpretation.

Peak identification:

Cu²⁺ absorbance peaks were observed at 562 nm, confirming the presence of the Cu²⁺-BCA

complex.

Zn²⁺ absorbance peaks appeared at 620 nm, corresponding to the Zn²⁺-Zincon complex.

Quantitative analysis based on spectrophotograms:

Using the calibration curves and measured peak absorbance values, the concentrations of

Cu²⁺ and Zn²⁺ in each sample were determined:

Sample Type

Cu²⁺ Concentration

(mg/L)

Zn²⁺ Concentration

(mg/L)

Wastewater

5.12

3.89

Industrial

Wastewater

4.78

4.21

Urban Sewage

5.45

4.02

Soil (Mining Area)

3.95

2.87

Detection limits and sensitivity:

The method’s Limit of Detection (LOD) and Limit of Quantification (LOQ) were

calculated:


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Cu²⁺ LOD: 0.19 mg/L, LOQ: 0.63 mg/L

Zn²⁺ LOD: 0.25 mg/L, LOQ: 0.83 mg/L

These results confirm that UV/Vis spectrophotometry is an effective technique for

detecting and quantifying Cu²⁺ and Zn²⁺ ions in environmental samples.

Discussion:

The determination of Cu²⁺ and Zn²⁺ ions in various environmental samples

using UV/Vis spectrophotometry provided valuable insights into the metal ion concentrations in

wastewater, industrial wastewater, urban sewage, and soil samples. The results obtained from the

spectrophotograms indicate the effectiveness of this method in detecting and quantifying metal

ions in different matrices.

Comparison of Cu²⁺ and Zn²⁺ concentrations across samples:

The highest Cu²⁺ concentration (5.45 mg/L) was detected in urban sewage, suggesting a

significant contribution from domestic and industrial waste. The lowest Cu²⁺ concentration (3.95

mg/L) was observed in soil samples from mining areas, which could be due to lower water

solubility and adsorption onto soil particles. Similarly, Zn²⁺ concentrations varied, with the highest

levels found in industrial wastewater (4.21 mg/L), likely due to industrial discharges containing

zinc-based compounds.

Effectiveness of UV/Vis spectrophotometry:

The UV/Vis spectrophotometric method proved to be a reliable analytical tool for metal

ion detection. The distinct absorption peaks at 562 nm (Cu²⁺) and 620 nm (Zn²⁺) allowed accurate

quantification. The low detection limits (LOD) of 0.19 mg/L for Cu²⁺ and 0.25 mg/L for Zn²⁺

demonstrate the method’s high sensitivity. However, spectral interference from other metal ions

and organic matter could impact accuracy, necessitating further sample purification or the use of

masking agents.

Comparison with other analytical techniques:

While atomic absorption spectroscopy (AAS) and inductively coupled plasma mass

spectrometry (ICP-MS) offer greater sensitivity and specificity, UV/Vis spectrophotometry

remains a cost-effective and accessible method for routine environmental monitoring. The results

obtained in this study are consistent with prior research, where UV/Vis spectrophotometry

effectively quantified Cu²⁺ and Zn²⁺ ions in aqueous samples.

Environmental implications:

Elevated levels of Cu²⁺ and Zn²⁺ in wastewater and urban sewage pose environmental risks.

Copper can be toxic to aquatic organisms, disrupting enzymatic processes, while excess zinc can


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accumulate in sediments, affecting microbial communities. The detected concentrations in this

study suggest that effective treatment processes are necessary before releasing wastewater into

natural water bodies.

Limitations and future directions:

Matrix interference: The presence of other metal ions and organic matter can affect

absorbance values, potentially leading to over- or underestimation of Cu²⁺ and Zn²⁺ concentrations.

Sample preparation: Improved filtration and complexation techniques can enhance

accuracy.

Alternative methods: Future studies should compare UV/Vis results with AAS or ICP-MS

to validate findings and improve detection capabilities.

The study demonstrates that UV/Vis spectrophotometry is an effective, cost-efficient

method for determining Cu²⁺ and Zn²⁺ concentrations in environmental samples. The method’s

sensitivity and ease of use make it suitable for routine monitoring, although further refinement

may be needed to reduce interference effects. The findings highlight the importance of controlling

metal ion pollution in industrial and urban wastewater to minimize environmental and ecological

risks.

Conclusion: This study successfully demonstrated the determination of Cu²⁺ and Zn²⁺ ions

in various environmental samples using UV/Vis spectrophotometry

.

The method provided

accurate and reliable quantification of these metal ions in wastewater, industrial wastewater, urban

sewage, and soil samples from a mining area.

The observed absorbance peaks at 562 nm for Cu²⁺

and 620 nm for Zn²⁺ confirmed the presence of the respective metal complexes, allowing for

precise concentration calculations.

The results indicate that Cu²⁺ and Zn²⁺ concentrations vary across sample types, with the

highest levels detected in urban sewage and industrial wastewater, respectively. These findings

highlight the impact of anthropogenic activities, particularly industrial discharges and domestic

wastewater, on environmental metal contamination. The study also underscores the importance of

effective wastewater treatment processes to mitigate heavy metal pollution.

While UV/Vis spectrophotometry is a cost-effective and accessible technique, its accuracy

can be affected by matrix interference from other metal ions and organic substances. Future studies

should explore alternative or complementary analytical methods, such as atomic absorption

spectroscopy (AAS) or inductively coupled plasma mass spectrometry (ICP-MS), to improve

detection sensitivity and specificity.


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Overall, this research reinforces the critical role of environmental monitoring in assessing

heavy metal contamination and emphasizes the need for sustainable pollution control measures to

protect water and soil quality.

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Эргашев Э. Ю., Латипова Ё. Л. К., Хамрокулова Ф. Р. К. ФОРМИРОВАНИЕ

СОВМЕСТНОЙ РАБОТЫ ПО МЕТОДИКЕ «INSERT» ПРИ ПРЕПОДАВАНИИ

ТЕМЫ «ФИЗИКО-ХИМИЧЕСКИЕ ИЗМЕНЕНИЯ» //Universum: психология и

образование. – 2025. – Т. 1. – №. 1 (127). – С. 64-68.

29.

Yuldoshevich E. E. et al. KIMYO FANINI O ‘QITISHDA, SINFLAR KESIMIDA KRITIK

VA KREATIV FIKRLASH KO ‘NIKMASINI RIVOJLANTIRISHNING ZAMONAVIY

STRATEGIYALARI VA METODLARIDAN FOYDALANISH //Ustozlar uchun. – 2024.

– Т. 61. – №. 1. – С. 8-15.

30.

Ravshanov M., Xudoyberdiyev B. TEACHING CHEMISTRY BASED ON DISTANCE

EDUCATION

TECHNOLOGIES

(SYNCHRONOUS

AND

ASYNCHRONOUS

TEACHING METHODS) //Modern Science and Research. – 2024. – Т. 3. – №. 6.

31.

Khusanov E. S. et al. Solubility of Components in the Acetic Acid–Triethanolamine–Water

System //Russian Journal of Inorganic Chemistry. – 2023. – Т. 68. – №. 11. – С. 1674-1680.


background image

ISSN:

2181-3906

2025

International scientific journal

«MODERN SCIENCE АND RESEARCH»

VOLUME 4 / ISSUE 2 / UIF:8.2 / MODERNSCIENCE.UZ

837

32.

Khusanov E., Shukhurov Z. STUDY OF SOLUBILITY PROPERTIES OF COMPONENTS

IN ACETATE UREA-TRIETHANOLAMINE-WATER SYSTEM //Journal of Chemical

Technology and Metallurgy. – 2024. – Т. 59. – №. 3. – С. 497-504.

33.

Artikovich O. K., Faxritdinovich E. F., Ergashboyevna E. M. GAZLAR TARKIBIDAGI

KISLORODNI ANIQLOVCHI SENSOR //Research Focus. – 2024. – Т. 3. – №. 5. – С.

197-202.’

34.

Эшқобилова М. Э., Эрданов Ф. Ф., Равшанов М. И. ТАБИИЙ ГАЗ (МЕТАН) НИ

АНИҚЛОВЧИ СЕНСОР (ЯЎС-СН4) НИНГ СИГНАЛИНИНГ БАРҚАРОРЛИГИ ВА

СЕЛЕКТИВЛИГИНИ ТЕКШИРИШ //Research Focus. – 2024. – Т. 3. – №. 9. – С. 24-29.

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